SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.053M) Tue Feb 23 02:07:33 2021 No. of days remaining = 364 Empirical Formula: C2 H16 N8 Cu Br6 = 33 atoms MERS=(1,1,1) MS=0.5 UHF CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Aminoguanidinium hexa-bromo-copper(ii) (TIVJEN) GEOMETRY OPTIMISED USING EIGENVECTOR FOLLOWING (EF). SCF FIELD WAS ACHIEVED HEAT OF FORMATION = -145.17579 KCAL/MOL = -607.41548 KJ/MOL H.o.F. per unit cell = -145.17579 KCAL, for 1 unit cells, unit cell = C2 H16 N8 CuBr6 TOTAL ENERGY = -3968.07103 EV ELECTRONIC ENERGY = -10938665.79109 EV CORE-CORE REPULSION = 10934697.72006 EV VOLUME OF UNIT CELL = 399.811 CUBIC ANGSTROMS DENSITY = 2.887 GRAMS/CC A = 8.064 ANGSTROMS B = 7.689 ANGSTROMS C = 7.841 ANGSTROMS ALPHA = 84.669 DEGREES BETA = 88.581 DEGREES GAMMA = 123.949 DEGREES GRADIENT NORM = 4.38114 = 0.76266 PER ATOM (SZ) = 0.500000 (S**2) = 0.752995 NO. OF ALPHA ELECTRONS = 59 NO. OF BETA ELECTRONS = 58 IONIZATION POTENTIAL = 10.892169 EV ALPHA SOMO LUMO (EV) = -10.892 -2.090 BETA SOMO LUMO (EV) = -10.893 -2.537 MOLECULAR WEIGHT = 695.1720 Pressure required to constrain translation vectors Tv( 34) Pressure: 0.05 GPa Tv( 35) Pressure: -0.07 GPa Tv( 36) Pressure: -0.08 GPa SCF CALCULATIONS = 13 WALL-CLOCK TIME = 2 MINUTES AND 29.268 SECONDS COMPUTATION TIME = 2 MINUTES AND 28.230 SECONDS FINAL GEOMETRY OBTAINED MERS=(1,1,1) MS=0.5 UHF CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Aminoguanidinium hexa-bromo-copper(ii) (TIVJEN) Cu -0.13177631 +1 -0.27158950 +1 0.10768576 +1 Br 1.20814434 +1 -2.09308611 +1 1.40707998 +1 Br -1.23630207 +1 0.62142597 +1 2.29919814 +1 Br 1.73156315 +1 1.50537413 +1 0.48325891 +1 Br -1.47988236 +1 1.55379516 +1 -1.18215989 +1 Br 0.98136620 +1 -1.18859052 +1 -2.07592205 +1 Br -1.99364932 +1 -2.04809710 +1 -0.28522724 +1 N -3.60797598 +1 0.99703458 +1 5.15804903 +1 N -3.07467914 +1 -0.91795713 +1 6.41145936 +1 C -3.98263028 +1 -0.11391311 +1 5.81994969 +1 N -5.30735868 +1 -0.64876835 +1 5.80178363 +1 N -6.38257569 +1 0.16554999 +1 5.29077889 +1 H -4.22435865 +1 1.55434083 +1 4.58710189 +1 H -2.62704537 +1 1.27159983 +1 5.10842175 +1 H -3.32606508 +1 -1.62997470 +1 7.09156830 +1 H -2.07793950 +1 -0.77094517 +1 6.28075255 +1 H -5.58921233 +1 -1.08470051 +1 6.71600840 +1 H -7.25648531 +1 -0.42222444 +1 5.37597398 +1 H -6.20412572 +1 0.35509544 +1 4.27686498 +1 H -6.52814182 +1 1.05800559 +1 5.82711332 +1 N -2.92364680 +1 -3.91459700 +1 4.27351037 +1 N -3.46592273 +1 -1.99630134 +1 3.03394920 +1 C -2.55377410 +1 -2.80123908 +1 3.61628212 +1 N -1.22808565 +1 -2.26820239 +1 3.61967697 +1 N -0.15442375 +1 -3.06040117 +1 4.17001636 +1 H -2.29002985 +1 -4.49779692 +1 4.80190156 +1 H -3.90315245 +1 -4.18358284 +1 4.34666485 +1 H -3.21358941 +1 -1.27347760 +1 2.36495427 +1 H -4.46196237 +1 -2.14248611 +1 3.16809583 +1 H -0.94526529 +1 -1.87697980 +1 2.68390956 +1 H 0.69990600 +1 -2.43939246 +1 4.11966766 +1 H -0.36442025 +1 -3.26294043 +1 5.17522228 +1 H 0.04339448 +1 -3.93820364 +1 3.62995580 +1 Tv -1.31768439 +1 0.83607984 +1 -7.91137429 +1 Tv 0.42586757 +1 5.88653305 +1 4.92758322 +1 Tv 7.58660241 +1 1.49391731 +1 -1.30364355 +1